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- W2064662372 abstract "Abstract An amphiphilic polymer brush with PB and PEO side chains is prepared by combined “grafting‐onto” and “grafting‐from”. The linear and star‐shaped heterografted copolymer synthesized is of controlled molecular weight and has a narrow molecular weight distribution ( M w / M n < 1.2). A DSC study of this heterografted copolymer containing crystalline and amorphous chains shows that it displays “fractionated crystallization” behavior. The study on isothermal crystallization kinetics of the copolymer is carried out in isothermal step crystallization (ISC) experiments, in which two crystallization exothermic peaks at low temperatures are observed. The critical micelle concentration (cmc) of the amphiphilic brush polymer in an aqueous solution is determined by a fluorescence technique. The results show that this amphiphilic brush forms aggregates in the system. magnified image" @default.
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- W2064662372 date "2013-07-23" @default.
- W2064662372 modified "2023-10-12" @default.
- W2064662372 title "Facile Synthesis of Amphiphilic Heterografted Copolymers with Crystalline and Amorphous Side Chains" @default.
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- W2064662372 doi "https://doi.org/10.1002/macp.201300255" @default.
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