Matches in SemOpenAlex for { <https://semopenalex.org/work/W2064688489> ?p ?o ?g. }
- W2064688489 endingPage "3597" @default.
- W2064688489 startingPage "3590" @default.
- W2064688489 abstract "Mica powders with ultrahigh specific surface areas (ca. 100 m2/g) were treated with aqueous solutions of peroxide radical initiators bearing a single cationic group to exchange the mica surface ions with initiator cations. The stability of the initiators, the adsorption isotherms on the mica, and the adsorption equilibrium constants were measured. The resulting materials initiate the polymerization of styrene at various conditions, forming bound polymer chains in amounts up to ca. 30 wt % polymer (ca. 55 vol %) with respect to the mica. The bound chains could be removed from the surface by extraction with good solvents for poly(styrene) only when the solvent contained ions for ion exchange. On the basis of kinetic evidence, the mechanism of grafting appears to be propagation of free radicals from the surface into the monomer solution, i.e., “growth from the surface”. The results differ strongly from those previously obtained with a dicationic surface-bound azo initiator, where grafting was shown to occur by “growth to the surface”." @default.
- W2064688489 created "2016-06-24" @default.
- W2064688489 creator A5008686290 @default.
- W2064688489 creator A5046126816 @default.
- W2064688489 creator A5046678254 @default.
- W2064688489 creator A5059462676 @default.
- W2064688489 creator A5066998262 @default.
- W2064688489 date "1999-05-06" @default.
- W2064688489 modified "2023-10-14" @default.
- W2064688489 title "Polymerization of Styrene with Peroxide Initiator Ionically Bound to High Surface Area Mica" @default.
- W2064688489 cites W1529320031 @default.
- W2064688489 cites W1965537738 @default.
- W2064688489 cites W1967340027 @default.
- W2064688489 cites W1973183902 @default.
- W2064688489 cites W1973808315 @default.
- W2064688489 cites W1974335561 @default.
- W2064688489 cites W1976105631 @default.
- W2064688489 cites W1981445799 @default.
- W2064688489 cites W1988884689 @default.
- W2064688489 cites W1991300753 @default.
- W2064688489 cites W1991845012 @default.
- W2064688489 cites W1997756985 @default.
- W2064688489 cites W1998504606 @default.
- W2064688489 cites W1999558979 @default.
- W2064688489 cites W2000369914 @default.
- W2064688489 cites W2004084518 @default.
- W2064688489 cites W2008651265 @default.
- W2064688489 cites W2013991498 @default.
- W2064688489 cites W2019439457 @default.
- W2064688489 cites W2035761071 @default.
- W2064688489 cites W2038893541 @default.
- W2064688489 cites W2040402192 @default.
- W2064688489 cites W2041525397 @default.
- W2064688489 cites W2045525303 @default.
- W2064688489 cites W2046381995 @default.
- W2064688489 cites W2047289481 @default.
- W2064688489 cites W2049146250 @default.
- W2064688489 cites W2052852767 @default.
- W2064688489 cites W2056418657 @default.
- W2064688489 cites W2056648038 @default.
- W2064688489 cites W2067820067 @default.
- W2064688489 cites W2074901393 @default.
- W2064688489 cites W2079797316 @default.
- W2064688489 cites W2080340301 @default.
- W2064688489 cites W2088763808 @default.
- W2064688489 cites W2091794004 @default.
- W2064688489 cites W2096147030 @default.
- W2064688489 cites W4247817404 @default.
- W2064688489 cites W2018333246 @default.
- W2064688489 doi "https://doi.org/10.1021/ma9813791" @default.
- W2064688489 hasPublicationYear "1999" @default.
- W2064688489 type Work @default.
- W2064688489 sameAs 2064688489 @default.
- W2064688489 citedByCount "49" @default.
- W2064688489 countsByYear W20646884892012 @default.
- W2064688489 countsByYear W20646884892013 @default.
- W2064688489 countsByYear W20646884892014 @default.
- W2064688489 countsByYear W20646884892015 @default.
- W2064688489 countsByYear W20646884892021 @default.
- W2064688489 countsByYear W20646884892022 @default.
- W2064688489 countsByYear W20646884892023 @default.
- W2064688489 crossrefType "journal-article" @default.
- W2064688489 hasAuthorship W2064688489A5008686290 @default.
- W2064688489 hasAuthorship W2064688489A5046126816 @default.
- W2064688489 hasAuthorship W2064688489A5046678254 @default.
- W2064688489 hasAuthorship W2064688489A5059462676 @default.
- W2064688489 hasAuthorship W2064688489A5066998262 @default.
- W2064688489 hasConcept C111998727 @default.
- W2064688489 hasConcept C150394285 @default.
- W2064688489 hasConcept C15920480 @default.
- W2064688489 hasConcept C159985019 @default.
- W2064688489 hasConcept C166940927 @default.
- W2064688489 hasConcept C178790620 @default.
- W2064688489 hasConcept C183882617 @default.
- W2064688489 hasConcept C184651966 @default.
- W2064688489 hasConcept C185592680 @default.
- W2064688489 hasConcept C188027245 @default.
- W2064688489 hasConcept C192562407 @default.
- W2064688489 hasConcept C2777566558 @default.
- W2064688489 hasConcept C2780995637 @default.
- W2064688489 hasConcept C2781038479 @default.
- W2064688489 hasConcept C2781048764 @default.
- W2064688489 hasConcept C44228677 @default.
- W2064688489 hasConcept C521977710 @default.
- W2064688489 hasConceptScore W2064688489C111998727 @default.
- W2064688489 hasConceptScore W2064688489C150394285 @default.
- W2064688489 hasConceptScore W2064688489C15920480 @default.
- W2064688489 hasConceptScore W2064688489C159985019 @default.
- W2064688489 hasConceptScore W2064688489C166940927 @default.
- W2064688489 hasConceptScore W2064688489C178790620 @default.
- W2064688489 hasConceptScore W2064688489C183882617 @default.
- W2064688489 hasConceptScore W2064688489C184651966 @default.
- W2064688489 hasConceptScore W2064688489C185592680 @default.
- W2064688489 hasConceptScore W2064688489C188027245 @default.
- W2064688489 hasConceptScore W2064688489C192562407 @default.
- W2064688489 hasConceptScore W2064688489C2777566558 @default.
- W2064688489 hasConceptScore W2064688489C2780995637 @default.
- W2064688489 hasConceptScore W2064688489C2781038479 @default.