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• W2064694609 abstract "The activity of Ce in Pd — Ce alloys was determined between 1000 and 1100 K by emf measurements on fluorine concentration cells with CeF3 as a solid electrolyte. The method of coulometric titration was used to deposit Ce on a thin Pd film and to control the composition of the alloys produced in situ. The system is characterized by pronounced negative deviations from ideal behavior which are attributed to the levelling of the Fermi energies upon the transfer of cerium valence electrons to the bands of the alloy. Including the lattice distortion as an additional effect, the thermodynamic behavior of Ce and other electropositive metals dissolved in Pd can be correlated and well described." @default.
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• W2064694609 date "1990-02-01" @default.
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• W2064694609 title "A Thermodynamic Study of Pd - Ce Alloys Using CeF3 as Electrolyte" @default.
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• W2064694609 doi "https://doi.org/10.1002/bbpc.19900940217" @default.
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