Matches in SemOpenAlex for { <https://semopenalex.org/work/W2064716691> ?p ?o ?g. }
- W2064716691 endingPage "2982" @default.
- W2064716691 startingPage "2973" @default.
- W2064716691 abstract "Acoustical absorption spectra between 10 kHz and 2 GHz are reported for various monosaccharides in water. With the exception of solutions of methyl-β-D-arabinopyranoside (0.5 mol/l) the spectra reveal absorption with relaxation characteristics in excess to the asymptotic high frequency absorption term. Up to three relaxation terms per spectrum emerge within the measuring frequency range. Regression analysis of the measured spectra in terms of a suitable analytical spectral function yields five relaxation regimes with relaxation times on the order of 1 μs, 100 ns, 10 ns, 1 ns, or 100 ps, respectively. These relaxation regimes are assigned to the chair–chair ring inversion, two modes of pseudorotation, an exocyclic side group isomerization and a molecular association mechanism. Particular emphasis is given to the ring inversion which is additionally verified by time resolved measurements of nonequilibrium tautomer systems, utilizing the coupling of the inversion to the carbohydrate mutarotation. Further evidence is derived from measurements of solutions of D-fructose in mixtures of ethanol and water." @default.
- W2064716691 created "2016-06-24" @default.
- W2064716691 creator A5077185677 @default.
- W2064716691 creator A5080359722 @default.
- W2064716691 creator A5085316486 @default.
- W2064716691 date "2002-02-15" @default.
- W2064716691 modified "2023-09-27" @default.
- W2064716691 title "Chair–chair conformational flexibility, pseudorotation, and exocyclic group isomerization of monosaccharides in water" @default.
- W2064716691 cites W1964179104 @default.
- W2064716691 cites W1973863628 @default.
- W2064716691 cites W1974212637 @default.
- W2064716691 cites W1982678106 @default.
- W2064716691 cites W1983666978 @default.
- W2064716691 cites W1984364795 @default.
- W2064716691 cites W1991892322 @default.
- W2064716691 cites W1992538967 @default.
- W2064716691 cites W1993549179 @default.
- W2064716691 cites W1997028494 @default.
- W2064716691 cites W1998074006 @default.
- W2064716691 cites W2000945960 @default.
- W2064716691 cites W2004338516 @default.
- W2064716691 cites W2006782826 @default.
- W2064716691 cites W2009704408 @default.
- W2064716691 cites W2010013656 @default.
- W2064716691 cites W2014247772 @default.
- W2064716691 cites W2014379191 @default.
- W2064716691 cites W2024418265 @default.
- W2064716691 cites W2030144512 @default.
- W2064716691 cites W2030411632 @default.
- W2064716691 cites W2035810795 @default.
- W2064716691 cites W2053280870 @default.
- W2064716691 cites W2058009992 @default.
- W2064716691 cites W2058805983 @default.
- W2064716691 cites W2064104387 @default.
- W2064716691 cites W2066757885 @default.
- W2064716691 cites W2068042262 @default.
- W2064716691 cites W2070325992 @default.
- W2064716691 cites W2071547670 @default.
- W2064716691 cites W2077062886 @default.
- W2064716691 cites W2077287792 @default.
- W2064716691 cites W2079877561 @default.
- W2064716691 cites W2083575622 @default.
- W2064716691 cites W2085543499 @default.
- W2064716691 cites W2093116771 @default.
- W2064716691 cites W2141519605 @default.
- W2064716691 cites W2154607161 @default.
- W2064716691 cites W2163356276 @default.
- W2064716691 cites W2515378524 @default.
- W2064716691 cites W2951061714 @default.
- W2064716691 cites W4205733760 @default.
- W2064716691 doi "https://doi.org/10.1063/1.1436123" @default.
- W2064716691 hasPublicationYear "2002" @default.
- W2064716691 type Work @default.
- W2064716691 sameAs 2064716691 @default.
- W2064716691 citedByCount "36" @default.
- W2064716691 countsByYear W20647166912012 @default.
- W2064716691 countsByYear W20647166912013 @default.
- W2064716691 countsByYear W20647166912015 @default.
- W2064716691 countsByYear W20647166912016 @default.
- W2064716691 countsByYear W20647166912017 @default.
- W2064716691 countsByYear W20647166912018 @default.
- W2064716691 countsByYear W20647166912022 @default.
- W2064716691 crossrefType "journal-article" @default.
- W2064716691 hasAuthorship W2064716691A5077185677 @default.
- W2064716691 hasAuthorship W2064716691A5080359722 @default.
- W2064716691 hasAuthorship W2064716691A5085316486 @default.
- W2064716691 hasConcept C118859902 @default.
- W2064716691 hasConcept C119824511 @default.
- W2064716691 hasConcept C121332964 @default.
- W2064716691 hasConcept C126661725 @default.
- W2064716691 hasConcept C1276947 @default.
- W2064716691 hasConcept C147597530 @default.
- W2064716691 hasConcept C15744967 @default.
- W2064716691 hasConcept C161790260 @default.
- W2064716691 hasConcept C178790620 @default.
- W2064716691 hasConcept C185592680 @default.
- W2064716691 hasConcept C23884331 @default.
- W2064716691 hasConcept C2776029896 @default.
- W2064716691 hasConcept C2779413573 @default.
- W2064716691 hasConcept C2780378348 @default.
- W2064716691 hasConcept C4839761 @default.
- W2064716691 hasConcept C48779969 @default.
- W2064716691 hasConcept C62520636 @default.
- W2064716691 hasConcept C71240020 @default.
- W2064716691 hasConcept C77805123 @default.
- W2064716691 hasConceptScore W2064716691C118859902 @default.
- W2064716691 hasConceptScore W2064716691C119824511 @default.
- W2064716691 hasConceptScore W2064716691C121332964 @default.
- W2064716691 hasConceptScore W2064716691C126661725 @default.
- W2064716691 hasConceptScore W2064716691C1276947 @default.
- W2064716691 hasConceptScore W2064716691C147597530 @default.
- W2064716691 hasConceptScore W2064716691C15744967 @default.
- W2064716691 hasConceptScore W2064716691C161790260 @default.
- W2064716691 hasConceptScore W2064716691C178790620 @default.
- W2064716691 hasConceptScore W2064716691C185592680 @default.
- W2064716691 hasConceptScore W2064716691C23884331 @default.
- W2064716691 hasConceptScore W2064716691C2776029896 @default.
- W2064716691 hasConceptScore W2064716691C2779413573 @default.