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- W2064723054 abstract "[{Rh(C5Me5)}2(OH)3][PF6] reacts with phenol to give [{Rh(C5Me5)}2(OPh)3][PF6](3), containing three µ-phenoxo-ligands. The related complexes [{Rh(C5Me5)}2(OH)3]X (X = Cl or OH) react with phenol to give [{Rh(C5Me5)(OPh)2(PhOH)2}n] which is formulated as the tri-µ-phenoxo-complex [{Rh(C5Me5)}2(OPh)3]-[(PhO)5H4](4), largely on the basis of the 13C n.m.r. spectra. The methyl hydrogens in (4)[but not in (3)] exchange very rapidly for deuterium in [2H6] acetone solution." @default.
- W2064723054 created "2016-06-24" @default.
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- W2064723054 date "1981-01-01" @default.
- W2064723054 modified "2023-09-23" @default.
- W2064723054 title "Pentamethylcyclopentadienyl-rhodium and -iridium complexes. Part 31. Tri-µ-phenoxo-rhodium complexes and a facile H/D exchange reaction" @default.
- W2064723054 doi "https://doi.org/10.1039/dt9810002335" @default.
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