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• W2064757634 abstract "Two single oxygen-bridged heterobimetallic oxides of Al(III) with group 4 metals (Ti, Hf) have been prepared. The reaction of LAlMeOH (1) [L = CH(N(Ar)(CMe))2, Ar = 2,6-iPr2C6H3] with dimethylmetallocenes of Ti and Hf in toluene (80 degrees C) and ether (room temperature), respectively, resulted in the formation of LAl(Me)(mu-O)M(Me)Cp2 [M = Ti (2), Hf (3)] in moderate to good yield. Compounds 2 and 3 were characterized by elemental analysis, IR, NMR (1H and 13C), EI-MS, and single-crystal X-ray structural analysis. Furthermore, compound 2 showed good catalytic activity in ethylene and styrene homopolymerization, while compound 3 is less active in ethylene polymerization. The styrene polymerization yields atactic polystyrene." @default.
• W2064757634 created "2016-06-24" @default.
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• W2064757634 date "2007-01-20" @default.
• W2064757634 modified "2023-09-29" @default.
• W2064757634 title "Synthesis, Structural Characterization, Catalytic Properties, and Theoretical Study of Compounds Containing an Al−O−M (M = Ti, Hf) Core" @default.
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• W2064757634 doi "https://doi.org/10.1021/ic060538r" @default.
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