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• W2064758973 abstract "The synthesis and characterization of the new zinc phthalocyanine derivatives, tetra- (non-peripheral, 5 ) and octa-(peripheral, 6) substituted with 2-mercaptopyridine and their respective quaternized derivatives ( 8 and 9 ) are reported. Photochemical and photophysical properties of the new complexes are compared with those of the previously reported peripherally tetra-substituted complexes 7 and 10 . The quaternized compounds exhibit excellent solubility in water, making them potential photosensitizers for use in photodynamic therapy (PDT) of cancer. Spectroscopic, aggregation, photophysical and photochemical properties of these complexes are also investigated and compared. Photophysical (fluorescence quantum yields and lifetimes) and photochemical (singlet oxygen and photodegradation quantum yield) properties of these phthalocyanine photosensitizers are very important for the assessment of these complexes as PDT agents. In this study, the effects of the position of the substituents and quaternization of the substituents on the photophysical and photochemical parameters of the zinc phthalocyanines are also reported. This study also showed that the water-soluble quaternized zinc phthalocyanines strongly bind to blood plasma proteins such as bovine serum albumin (BSA). ► Synthesis of non-ionic and water soluble quaternized cationic zinc phthalocyanines. ► Photophysical and photochemical properties in DMSO and water. ► Bovine serum albumin binding properties. ► Potential for photodynamic therapy." @default.
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• W2064758973 date "2011-11-01" @default.
• W2064758973 modified "2023-10-16" @default.
• W2064758973 title "Water-soluble quaternized mercaptopyridine-substituted zinc-phthalocyanines: Synthesis, photophysical, photochemical and bovine serum albumin binding properties" @default.
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• W2064758973 doi "https://doi.org/10.1016/j.dyepig.2011.02.007" @default.
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