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- W2064795529 abstract "In this article we show that iron perchlorinated phthalocyanine (FePcCl16), adsorbed on an OPG electrode, acts as a catalyst for the electrooxidation of 2-mercaptoethanol (R-SH), lowering the overpotential of the reaction by near 0.3 V, compared to the unmodified OPG. A Tafel slope close to 0.12 V/decade was observed, indicating that the first electron-transfer is rate determining. Chemical orders of one in R-SH and in OH− are obtained. The linearity of a plot of log I vs. log [RSH] indicates that this system could have potential applications in the amperometric detection of thiols." @default.
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- W2064795529 date "1998-07-01" @default.
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- W2064795529 title "Catalytic Electrooxidation of 2-Mercaptoethanol on Perchlorinated Iron Phthalocyanine Adsorbed on a Graphite Electrode" @default.
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- W2064795529 doi "https://doi.org/10.1002/(sici)1521-4109(199807)10:8<571::aid-elan571>3.0.co;2-7" @default.
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