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- W2064831761 abstract "Abstract Lanthanide complexes of the types Ln(sah)(OAc)·xH2O and Ln′(Hsah)2(X)·xH2O [Ln=Y, La, Nd, Gd, Tb and Dy; Ln′=Pr and Sm, X=NO3 and Cl; H2sah=salicylaldehyde anthranoyl hydrazone were synthesized and characterized by various physico-chemical techniques. The complexes are coloured and highly soluble in methanol, DMSO and DMF. Dehydration studies indicate the presence of both lattice-held and coordinated water molecules. IR, electronic and 1H NMR spectra have been recorded to establish the bonding sites of the ligand. Solution-state conductance measurements indicate the non-electrolytic nature of all of the complexes while solid-state electrical conductivity studies show Nd(sah)(OAc)·4H2O to be a semiconductor. Optical band gap measurements show the Pr, Sm and Dy complexes are direct band gap materials. X-ray diffraction patterns of selected complexes indicate orthorhombic structures." @default.
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- W2064831761 date "2002-09-04" @default.
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- W2064831761 title "SYNTHESIS AND STRUCTURAL STUDIES OF SOME LANTHANIDE COMPLEXES OF SALICYLALDEHYDE ANTHRANOYL HYDRAZONE" @default.
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- W2064831761 doi "https://doi.org/10.1081/sim-120003216" @default.
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