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• W2064908713 abstract "Superconducting properties of the binary Chevrel phase Mo3Se4 have been modified by rare-earth doping. Very small quantities of lanthanides make the Tc of this compound to increase by almost 1 K (from 6.45 to 7.2 K) for the bigger ions, while no effects are seen for heavy rare earths (smaller ions). A clear correlation has been established between Tc and the ionic radius of the dopant. The domain of existence of the doped phase (denoted herein as (Mo3Se4)REx) was determined from X-ray diffraction and χAC susceptibility techniques. It is bounded by a Mo/Se ratio equal to or slightly larger than 0.75 and by a maximum content of rare earth of about 1–1.5 at% RE (compared to 6–7 at% RE in the ternary phase RExMo6Se8). Crystallographic, superconducting and some magnetic data are given for several members of the series (REY, La, Ce, Nd, Sm, Eu, Gd, Dy, Ho, Er and Yb). Three interesting cases are outlined since they behave completely different as in the ternary-phase counterparts: cerium and divalent europium show some of the largest increase of Tc, while ytterbium (in a trivalent oxidation state) does not affect the critical temperature of the matrix." @default.
• W2064908713 created "2016-06-24" @default.
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• W2064908713 date "1996-11-01" @default.
• W2064908713 modified "2023-10-02" @default.
• W2064908713 title "Rare-earth doping of the Mo3Se4 superconductor" @default.
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• W2064908713 doi "https://doi.org/10.1016/s0921-4526(96)00489-9" @default.
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