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- W2064911631 abstract "Abstract A new class of cationic α‐cyclodextrins bearing 2‐hydroxy‐3‐trimethylammoniopropyl groups has been synthesised. We investigated their efficiency as mass‐transfer promoters in a biphasic hydroformylation reaction catalysed by a rhodium trisulfonated triphenylphosphine system. These cationic α‐cyclodextrins greatly increased the reaction rate, the chemoselectivity, and, surprisingly, the linear‐to‐branched aldehyde ratio. We attributed this unexpected enhancement of the linear‐to‐branched aldehyde ratio to the in situ formation of new catalytic supramolecular species obtained by ion‐exchange between the catalyst ligand and the cationic α‐cyclodextrins." @default.
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- W2064911631 date "2005-10-13" @default.
- W2064911631 modified "2023-10-17" @default.
- W2064911631 title "Rhodium Complexes Non‐Covalently Bound to Cyclodextrins: Novel Water‐Soluble Supramolecular Catalysts for the Biphasic Hydroformylation of Higher Olefins" @default.
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- W2064911631 doi "https://doi.org/10.1002/chem.200500337" @default.
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