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• W2064915079 abstract "The dielectric polarizations, i.e. spontaneous, linear, and second order non-linear polarizations, generated from Langmuir monolayers comprised of rod-shaped molecules were analyzed, and represented as functions of the orientational order parameters S1,S2, and S3 (Sn=〈Pn(cos⁡θ)〉,θ: molecular tilt angle, 〈〉: thermodynamic average, Pn(cos⁡θ): Legendre polynomial of n th order). It has been shown that the Maxwell displacement current (MDC), Brewster angle reflectometry (BAR), and optical second harmonic generation (SHG), which are attributed to the spontaneous, linear, and non-linear polarization, respectively, are capable of detecting the orientational order parameter S1,S2, and S3 of Langmuir monolayers. An experiment using the MDC-BAR-SHG was conducted on Langmuir monolayers comprised of 4-octyl-4′-cyanobiphenyl rod-shaped molecules. It is shown that the MDC-BAR-SHG measurements are useful to investigate the orientational structure of Langmuir monolayers." @default.
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• W2064915079 date "2006-08-01" @default.
• W2064915079 modified "2023-10-17" @default.
• W2064915079 title "Measurement of Dielectric Polarizations for Analyzing the Orientational Order of Langmuir Monolayers" @default.
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• W2064915079 doi "https://doi.org/10.1016/j.colsurfa.2005.10.084" @default.
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