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• W2064937506 startingPage "2692" @default.
• W2064937506 abstract "Biodegradable elastomeric poly(trimethylene carbonate) (PTMC) networks were efficiently formed by gamma irradiating the linear polymer in the presence of pentaerythritol triacrylate (PETA). The properties of networks formed upon irradiation of PTMC films containing (0, 1, 5 wt %) PETA as a cross-linking aid were evaluated. The gel contents and network densities increased with increasing PETA contents, irradiation dose, and initial polymer molecular weights. At a dose of 25 kGy, networks with gel fractions up to 0.96 could be obtained. The networks were noncytotoxic, had elastic moduli below 10.7 MPa and high tensile strengths of up to 37.7 MPa. The incorporation of PETA also improved the resistance to creep and to tear propagation significantly, resulting in permanent set values that were as low as 0.9% strain and tear strengths up to 9.3 ± 2.0 N/mm. Furthermore, the enzymatic erosion rates of the networks could be decreased from 12.0 ± 2.9 to 3.0 ± 1.6 μm/day. These biodegradable elastomeric PTMC networks may be utilized in a broad range of medical applications." @default.
• W2064937506 created "2016-06-24" @default.
• W2064937506 creator A5017040227 @default.
• W2064937506 creator A5036523702 @default.
• W2064937506 creator A5081367381 @default.
• W2064937506 date "2010-09-14" @default.
• W2064937506 modified "2023-10-02" @default.
• W2064937506 title "Biodegradable Elastomeric Networks: Highly Efficient Cross-Linking of Poly(trimethylene carbonate) by Gamma Irradiation in the Presence of Pentaerythritol Triacrylate" @default.
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• W2064937506 doi "https://doi.org/10.1021/bm1007234" @default.
• W2064937506 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20839883" @default.
• W2064937506 hasPublicationYear "2010" @default.
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