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• W2064946720 endingPage "1661" @default.
• W2064946720 startingPage "1658" @default.
• W2064946720 abstract "In order to develop new methyl substituted chiral building blocks which are useful for the synthesis of methyl branched natural products, the enantioselective bioreduction of an exo-methylene to a methyl group was investigated. 4-Acetoxy-2-methylene-1-butanol 3 was prepared from itaconic acid over four steps and converted to the chiral alcohol (R)-4-acetoxy-2-methyl-1-butanol 4, by growing cells of Pseudomonas putida. The bioconversion achieved a high enantioselectivity (92% ee) and a high chemical yield (65%) within a relatively short reaction time (18–20 h)." @default.
• W2064946720 created "2016-06-24" @default.
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• W2064946720 date "2011-09-01" @default.
• W2064946720 modified "2023-10-02" @default.
• W2064946720 title "Chemo-biological preparation of the chiral building block (R)-4-acetoxy-2-methyl-1-butanol using Pseudomonas putida" @default.
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• W2064946720 doi "https://doi.org/10.1016/j.tetasy.2011.09.019" @default.
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