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- W2064961729 abstract "Four novel five-coordinated Sn(IV) and Pb(IV) complexes of 2,6-bis(2‘-indolyl)pyridine (H2bip) and 2,6-bis[2‘-(7-azaindolyl)]pyridine (H2bap) were synthesized. These four complexes have the formulas Sn(bip)Ph2 (1), Sn(bap)Ph2 (2), Pb(bip)Ph2 (3), and Pb(bap)Ph2 (4), respectively. The structures were determined by single-crystal X-ray diffraction. In the complexes, the metal centers are tridentately chelated by the bip or the bap ligand and further coordinated by two phenyl groups, resulting in a distorted-trigonal-bipyramidal geometry. These complexes display interesting extended π−π stack structures in the solid state. Complexes 1 and 2 are luminescent at room temperature in solution and the solid state. At 77 K in THF solution, all four complexes display both blue-green fluorescent and orange-red phosphorescent emissions, which originate from ligand-centered π → π* transitions. The Sn(IV) and Pb(IV) centers play a key role in enhancing phosphorescent emission of the bip and bap ligands." @default.
- W2064961729 created "2016-06-24" @default.
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- W2064961729 date "2003-08-28" @default.
- W2064961729 modified "2023-09-26" @default.
- W2064961729 title "Novel Phosphorescent Cyclometalated Organotin(IV) and Organolead(IV) Complexes of 2,6-Bis(2‘-indolyl)pyridine and 2,6-Bis[2‘-(7-azaindolyl)]pyridine" @default.
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- W2064961729 doi "https://doi.org/10.1021/om030404a" @default.
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