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- W2064994020 abstract "The purpose of this study was to quantitate the transport behavior of several organic solutes in matrix systems composed of micron-size hexadecane droplets dispersed in an aqueous gelatin gel where the oil-water interfacial barrier to transport was expected to play an important role. Two interrelated experiments were conducted. The first was the one-dimensional aqueous uptake of the solute by the matrix which was a continuous layer placed at the bottom of a beaker. The other experiment was solute uptake and release from aggregates of oil droplets suspended in an aqueous medium. Solutes investigated were14C-labeled cholesterol, diethylphthalate,14C-labeled octanol, and14C-labeled progesterone. The data have been analyzed by various physical models. It was found that cholesterol transport essentially was controlled by the oil-water interfacial barrier in both kinds of experiments—even when the matrix thickness was as large as 3.7 mm. For the other solutes, the oil-water interfacial barriers were found to be controlling in the experiments with aggregates (10-1000 μ). However, in the experiments with the continuous matrix layers, bulk matrix diffusion factors as well as the oil-water interphase transport were found to be important for these solutes. The techniques developed in this investigation should be useful: (a) in the quantitation of interfacial barriers in oil-water interphase transport of solutes, and (b) in the separation of various bulk diffusional resistances from interfacial resistances in complex multiphase matrices." @default.
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- W2064994020 title "Interfacial Barriers in Interphase Transport III: Transport of Cholesterol and Other Organic Solutes into Hexadecane–Gelatin–Water Matrices" @default.
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- W2064994020 doi "https://doi.org/10.1002/jps.2600590516" @default.
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