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• W2065001022 abstract "Abstract 13C and 31P NMR parameters were obtained for phosphomycin in water solution. The pH dependence of chemical shifts was used to calculate the pK of the second deprotonation process (pK2 = 6.4). The pH dependence of 13C[sbnd]31P and 13P[sbnd]31H coupling constant was pointing to a change in dihedral angles and hence in the geometry of phosphomycin during deprotonation. The pH dependences of 31P spin-lattice relaxation rates and 13P[sbnd]{1H} NOEs were interpreted in terms of relative weigth of the 31P-1H dipolar interaction in determining the relaxation mechanism." @default.
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• W2065001022 date "1989-04-01" @default.
• W2065001022 modified "2023-10-14" @default.
• W2065001022 title "13C and31P NMR Studies of Phosphomycin, A Phosphonate Antibiotic" @default.
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• W2065001022 doi "https://doi.org/10.1080/00387018908053886" @default.
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