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• W2065001227 abstract "A mechanistic investigation of the Pd-catalyzed conversion of aryl triflates to fluorides is presented. Studies reveal that C–F reductive elimination from a LPdII(aryl)F complex (L = t-BuBrettPhos or RockPhos) does not occur when the aryl group is electron rich. Evidence is presented that a modified phosphine, generated in situ, serves as the actual supporting ligand during catalysis with such substrates. A preliminary study of the reactivity of a LPdII(aryl)F complex based on this modified ligand is reported." @default.
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• W2065001227 date "2011-10-21" @default.
• W2065001227 modified "2023-09-24" @default.
• W2065001227 title "Evidence for in Situ Catalyst Modification during the Pd-Catalyzed Conversion of Aryl Triflates to Aryl Fluorides" @default.
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• W2065001227 doi "https://doi.org/10.1021/ja208461k" @default.
• W2065001227 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3354724" @default.
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