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• W2065034821 abstract "The oxidation products of a number of 4- and 5-monosubstituted and 4,6-disubstituted pyrogallols are discussed. 4-Alkylpyrogallols yield the corresponding 4′,7-dialkylpurpurogallins and the structures of the products resulting from the further oxidation of these compounds with alkaline hydrogen peroxide are elucidated. Oxidation of 5-mono and 4,6-dialkylpyrogallol derivatives yield characteristic white and yellow dimers respectively. Evidence is presented in favour of a tricyclododecane formulation for the former and a dibenzodioxin structure for the latter type of dimer. The transformation of the dibenzodioxin dimers to benzocyclopentadioxepin isomers on treatment with base is described." @default.
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• W2065034821 date "1967-01-01" @default.
• W2065034821 modified "2023-10-18" @default.
• W2065034821 title "The oxidation of some pyrogallol and purpurogallin derivatives" @default.
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• W2065034821 doi "https://doi.org/10.1016/0040-4020(67)85149-4" @default.
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