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- W2065059675 abstract "Abstract 1. 1. The major phosphatide in the extremely halophilic bacterium, Halobacterium cutirubrum , has been isolated by a combination of solvent fractionation, precipitation through the barium salt, and final purification as the sodium salt. 2. 2. Analytical and degradative data showed the phosphatide to be a phosphatidyl glycerophosphate with two long-chain ether groups instead of fatty acid ester groups. 3. 3. Both long-chain groups were found to be identical and were shown by comparison of infrared, nuclear magnetic resonance, and mass spectra with those of dihydrophytyl derivatives to have the structure 3,7,11,15-tetramethylhexadecyl. The two long-chain groups are joined by ether linkages to the α, β-positions of l -glycerol. 4. 4. The structure proposed for the major phosphatide in H. cutirubrum is therefore :2,3- di -0-[3′,7′,11′,15′-tetramethylhexadecyl]-glyceryl-1-phosphoryl-[1Prime;(3Prime;)-glyceryl-3Prime;(1Prime;)-phosphate], in the notation of Hirschmann. 5. 5. Possible biochemical and physiological functions of this unusual phosphatide in the halophile cell are discussed." @default.
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- W2065059675 date "1965-04-01" @default.
- W2065059675 modified "2023-09-27" @default.
- W2065059675 title "A diether analog of phosphatidyl glycerophosphate in Halobacterium cutirubrum" @default.
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- W2065059675 doi "https://doi.org/10.1016/0005-2760(65)90119-0" @default.
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