Matches in SemOpenAlex for { <https://semopenalex.org/work/W2065131705> ?p ?o ?g. }
- W2065131705 endingPage "9927" @default.
- W2065131705 startingPage "9918" @default.
- W2065131705 abstract "The anionic gold(I) complexes [1-(Ph(3)PAu)-closo-1-CB(11)H(11)](-) (1), [1-(Ph(3)PAu)-closo-1-CB(9)H(9)](-) (2), and [2-(Ph(3)PAu)-closo-2-CB(9)H(9)](-) (3) with gold-carbon 2c-2e sigma bonds have been prepared from [AuCl(PPh(3))] and the respective carba-closo-borate dianion. The anions have been isolated as their Cs(+) salts and the corresponding [Et(4)N](+) salts were obtained by salt metathesis reactions. The salt Cs-3 isomerizes in the solid state and in solution at elevated temperatures to Cs-2 with DeltaH(iso)=(-75+/-5) kJ mol(-1) (solid state) and DeltaH( not equal)=(118+/-10) kJ mol(-1) (solution). The compounds were characterized by vibrational and multi-NMR spectroscopies, mass spectrometry, elemental analysis, and differential scanning calorimetry. The crystal structures of [Et(4)N]-1, [Et(4)N]-2, and [Et(4)N]-3 were determined. The bonding parameters, NMR chemical shifts, and the isomerization enthalpy of Cs-3 to Cs-2 are compared to theoretical data." @default.
- W2065131705 created "2016-06-24" @default.
- W2065131705 creator A5044847247 @default.
- W2065131705 creator A5054695527 @default.
- W2065131705 date "2009-09-23" @default.
- W2065131705 modified "2023-10-11" @default.
- W2065131705 title "Anionic Gold(I) Complexes—Twelve‐ and Ten‐Vertex Monocarba‐<i>closo</i>‐borate Anions with Carbon–Gold σ Bonds" @default.
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