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• W2065132225 endingPage "A537" @default.
• W2065132225 startingPage "A531" @default.
• W2065132225 abstract "In commercial Fe-based batteries the Fe2+/Fe3+ oxidation states are used, however by also utilizing the Fe4+ oxidation state, intercalation of up to two Li ions per Fe ion could be possible. In this study, we investigate whether Fe4+ can be formed and stabilized in β-Li3Fe2(PO4)3. The work includes in situ synchrotron X-ray powder diffraction studies (XRPD) during charging of β-Li3Fe2(PO4)3 up to 5.0 V vs. Li/Li+. A novel capillary-based micro battery cell for in situ XRPD has been designed for this. During charge, a plateau at 4.5 V was found and a small contraction in volume was observed, indicating some Li ion extraction. The volume change of the rhombohedral unit cell is anisotropic, with a decrease in the a parameter and an increase in the c parameter during the Li ion extraction. Unfortunately, no increased discharge capacity was observed and Mössbauer spectroscopy showed no evidence of Fe4+ formation. Oxidation of the organic electrolyte is inevitable at 4.5 V but this alone cannot explain the volume change. Instead, a reversible oxygen redox process (O2− → O−) could possibly explain and charge compensate for the reversible extraction of lithium ions from β-Li3Fe2(PO4)3." @default.
• W2065132225 created "2016-06-24" @default.
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• W2065132225 date "2015-01-01" @default.
• W2065132225 modified "2023-10-14" @default.
• W2065132225 title "In Situ Studies of Fe⁴⁺Stability in<i>β</i>-Li₃Fe₂(PO₄)₃Cathodes for Li Ion Batteries" @default.
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• W2065132225 doi "https://doi.org/10.1149/2.0141504jes" @default.
• W2065132225 hasPublicationYear "2015" @default.
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