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• W2065137951 abstract "In the presence of small amounts of 2,2-dialkyl-, 2,2,3-trialkyl-, or 2,2,3,3-tetraalkyl substituted epoxides such as isobutylene oxide, 1,2-limonene oxide, and 2,2,3,3,-tetramethyl oxirane, the photoinitiated cationic ring-opening polymerizations of 3,3-disubstituted oxetanes are dramatically accelerated. The acceleration affect was attributed to an increase in the rate of the initiation step of these latter monomers. Both mono- and disubstituted oxetane monomers are similarly accelerated by the above-mentioned epoxides to give crosslinked network polymers. The potential for the use of such “kick-started” systems in applications such as coatings, adhesives, printing inks, dental composites and in three-dimensional imaging is discussed. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 2934–2946" @default.
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• W2065137951 date "2014-08-08" @default.
• W2065137951 modified "2023-09-27" @default.
• W2065137951 title "“Kick-Starting” oxetane photopolymerizations" @default.
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• W2065137951 doi "https://doi.org/10.1002/pola.27329" @default.
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