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- W2065152095 abstract "We report results of experimental and theoretical lattice-dynamics studies on scandium orthovanadate up to 35 GPa. Raman-active modes of the low-pressure zircon phase are measured up to 8.2 GPa, where the onset of an irreversible zircon-to-scheelite phase transition is detected. Raman-active modes in the scheelite structure are observed up to 16.5 GPa. Beyond 18.2 GPa we detected a gradual splitting of the ${E}_{g}$ modes of the scheelite phase, indicating the onset of a second phase transition. Raman symmetries, frequencies, and pressure coefficients in the three phases of ScVO${}_{4}$ are discussed in the light of ab initio lattice-dynamics calculations that support the experimental results. The results on all the three phases of ScVO${}_{4}$ are compared with those previously reported for related orthovanadates." @default.
- W2065152095 created "2016-06-24" @default.
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- W2065152095 date "2011-02-25" @default.
- W2065152095 modified "2023-10-18" @default.
- W2065152095 title "High-pressure study of ScVO<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow /><mml:mrow><mml:mn>4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>by Raman scattering and<i>ab initio</i>calculations" @default.
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- W2065152095 doi "https://doi.org/10.1103/physrevb.83.064111" @default.
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