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- W2065157037 abstract "Abstract UV absorption of the - slightly unsymmetric - dibromo- and diiodotetrafluorobutane is localized in the end groups. We photolysed these molecules at 248 and 308 nm in the presence of various radical scavengers. In the gas phase, the dissociation probability of the CH 2 -X and CF 2 -X groups is proportional to their (wavelength-dependent) absorption cross sections, i.e. the photolysis is bond selective. This implies that in gas phase, energy redistribution cannot compete in rate with dissociation. In solution the selectivity is slightly reduced in the case of X = Br." @default.
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- W2065157037 date "1990-07-01" @default.
- W2065157037 modified "2023-09-26" @default.
- W2065157037 title "Bond-selective photodissociation of CX (X = Br,I) in XC2H4C2F4X" @default.
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- W2065157037 doi "https://doi.org/10.1016/0301-0104(90)80092-c" @default.
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