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• W2065161839 endingPage "8440" @default.
• W2065161839 startingPage "8432" @default.
• W2065161839 abstract "Thermodynamic standard Gibbs energies of transfer of alkali metal cations related to Cs+ cation [ΔtG°,*(Cs+) − [ΔtG°,*(M+)] between several mutually saturated solvents of the type water−solvent were calculated from determined extraction exchange constants Kexch°,*(Cs+/M+). The used liquid−liquid extraction method with radioactive tracing by 137Cs permits attaining higher precision of the values as compared to the methods used up to now. The data for o-nitrophenyloctyl ether, 1,2-dichloroethane, and 1-octanol were compared with literature sources and recommended absolute values of ΔtG°,*(M+) are reported. For dissociating solvents, the dependences of [ΔtG°,*(Cs+) − [ΔtG°,*(M+)] on Gibbs energy of hydration of an ion, ΔGhydr° are straight lines either for four cations Cs+, Rb+, K+, and Na+ (nitrosolvents) or for three cations Cs+, Rb+, and K+ (1,2-dichloroethane and 1-octanol). The hydration of Na+ and still more of Li+ in the water-saturated organic phase is apparent from the results. This manifests for high-water-content equilibrium 1-octanol even in a reversal of the values [i.e., ΔtG°,*(Li+) being more negative than ΔtG°,*(Na+)], although for Cs+, Rb+, and K+, the general trend is conserved. Water-saturated 1-octanol is thus slightly less basic than water, but the overall selectivity is very low. For one studied nondissociating solvent, dioctyl sebacate, the trend of the dependences of log Kexch°,*(CsB/M+) on ΔGhydr° is similar to that of Kexch°,*(Cs+/M+) for polar solvents, but different for different anions B, thus reflecting ion association in the organic phase." @default.
• W2065161839 created "2016-06-24" @default.
• W2065161839 creator A5015687893 @default.
• W2065161839 creator A5034956583 @default.
• W2065161839 creator A5035250902 @default.
• W2065161839 date "2006-04-01" @default.
• W2065161839 modified "2023-09-25" @default.
• W2065161839 title "Gibbs Energies of Transfer of Alkali Metal Cations between Mutually Saturated Water−Solvent Systems Determined from Extraction Experiments with Radiotracer ¹³⁷Cs" @default.
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• W2065161839 doi "https://doi.org/10.1021/jp060318z" @default.
• W2065161839 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16623529" @default.
• W2065161839 hasPublicationYear "2006" @default.
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