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- W2065165720 abstract "The O,O-dibenzyl-S-glycosyl phosphothioite derived from 3,4,6-tri-O-acetyl-2-acetamido-2-deoxy-1-thio-alpha-D-glucopyranose rearranges under the influence of triethylborane and air to provide the corresponding 1-C-pyranosyl-O,O-dibenzylphosphonothioate, a new type of carbohydrate derivative. The isomeric beta phosphothioite is compared, and evidence of a radical chain mechanism for the Pudovik rearrangement is presented." @default.
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- W2065165720 date "2007-03-01" @default.
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- W2065165720 title "The anomeric Pudovik rearrangement" @default.
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- W2065165720 doi "https://doi.org/10.1016/j.tetlet.2007.01.081" @default.
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