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- W2065172608 abstract "The title cobalt(II) coordination polymers, [Co3(C9H3O6)2(C14H14N4)3]n, (I), and {[Co3(C9H3O6)2(C14H14N4)3(H2O)2]·H2O}n, (II), present very different coordination and packing properties in spite of the ligand similarity. In (I), three crystallographically distinct CoII cations are all four-coordinated by O2N2 donor sets in distorted tetrahedral geometries. The CoII centres are connected by benzene-1,3,5-tricarboxylate (BTC) anions and 1,3-bis(imidazol-1-ylmethyl)benzene (L1) ligands into a (64.82)2(86)(6.82)2 topology framework. The structure of (II) contains two kinds of crystallographically unique CoII cations. One Co atom lies on a symmetry centre and is six-coordinated by an O4N2 donor set, and the other Co atom is four-coordinated by an O2N2 donor set. The CoII centres are connected by BTC anions and 1,4-bis(imidazol-1-ylmethyl)benzene (L2) ligands into a (62.84)2(64.82)(63)2 framework." @default.
- W2065172608 created "2016-06-24" @default.
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- W2065172608 date "2007-12-14" @default.
- W2065172608 modified "2023-09-26" @default.
- W2065172608 title "Poly[bis(μ<sub>3</sub>-benzene-1,3,5-tricarboxylato-κ<sup>3</sup><i>O</i><sup>1</sup>:<i>O</i><sup>3</sup>:<i>O</i><sup>5</sup>)tris[μ<sub>2</sub>-1,3-bis(imidazol-1-ylmethyl)benzene-κ<sup>2</sup><i>N</i>:<i>N</i>′]tricobalt(II)] and poly[[diaquabis(μ<sub>3</sub>-benzene-1,3,5-tricarboxylato-κ<sup>3</sup><i>O</i><sup>1</sup>:<i>O</i><sup>3</sup>:<i>O</i><sup>5</sup>)tris[μ<sub>2</sub>-1,4-bis(imidazol-1-ylmethyl)benzene-κ<sup>2</sup><i>N</i>:<i>N</i>′]tricobalt(II)] monohydrate]" @default.
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- W2065172608 doi "https://doi.org/10.1107/s0108270107059124" @default.
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