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- W2065179478 abstract "Reaction of [Au3(dmmp)2][CIO4]3 with an excess of dmmp [bis(dimethylphosphinomethyl)methylphosphine] in methanol yielded [Au3(dmmp)3][CIO4]3 in almost quantitative yield. Excitation of a degassed acetonitrile solution of [Au3(dmmp)3]3+ at λ > 350 nm resulted in intense phosphorescence (λem= 625 nm, τ0= 2.2 ± 0.2 µs). A comparison between the electronic absorption and emission spectra of [Au3(dmmp)3]3+ and [Au2(dmpm)3]2+[dmpm = bis(dimethylphosphino)methane] has been made. The assignment of the lowest electronic excited state in the (AuP3)n system has been suggested to be 3[(dδ*)(pσ)]. The excited-state redox potentials of [Au3(dmmp)3]3+* and [Au2(dmpm)3]2+* have been determined through oxidative quenching experiments with a series of pyridinium acceptors of variable reduction potential." @default.
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- W2065179478 date "1993-01-01" @default.
- W2065179478 modified "2023-10-16" @default.
- W2065179478 title "Synthesis, spectroscopy and excited-state redox properties of novel luminescent trinuclear three-co-ordinate gold(I) phosphine complexes" @default.
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- W2065179478 doi "https://doi.org/10.1039/dt9930002097" @default.
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