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- W2065186997 abstract "The effect of amorphous (am-), monoclinic (m-), and tetragonal (t-) ZrO2 phase on the physicochemical and catalytic properties of supported Cu catalysts for ethanol conversion was studied. The electronic parameters of Cu/ZrO2 were determined by in situ XAS, and the surface properties of Cu/ZrO2 were defined by XPS and DRIFTS of CO-adsorbed. The results demonstrated that the kind of ZrO2 phase plays a key role in the determination of structure and catalytic properties of Cu/ZrO2 catalysts predetermined by the interface at Cu/ZrO2. The electron transfer between support and Cu surface, caused by the oxygen vacancies at m-ZrO2 and am-ZrO2, is responsible for the active sites for acetaldehyde and ethyl acetate formation. The highest selectivity to ethyl acetate for Cu/m-ZrO2 catalyst up to 513 K was caused by the optimal ratio of Cu0/Cu+ species and the high density of basic sites (O2−) associated with the oxygen mobility from the bulk m-ZrO2." @default.
- W2065186997 created "2016-06-24" @default.
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- W2065186997 date "2013-11-01" @default.
- W2065186997 modified "2023-10-16" @default.
- W2065186997 title "Effect of the ZrO2 phase on the structure and behavior of supported Cu catalysts for ethanol conversion" @default.
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- W2065186997 doi "https://doi.org/10.1016/j.jcat.2013.06.022" @default.
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