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- W2065203669 abstract "Abstract Syntheses of 1-[(1′,2′-distearoyl-glyceryl)-phosphoryl]-3-L-lysyl-glycerol (XII) and 1-[(1′,2′-distearoyl-glyceryl)-phosphoryl]-2-L-lysyl-glycerol (XXII), as well as of 1-L-lysyl- 3-[(1′,2′-distearoyl-glyceryl)-phosphoryl]-glycerol (XVI) are described, the first two substances having the same configuration at all asymmetric atoms as the natural lysyl ester of phosphatidyl glycerol. It was shown that the α- and β-lysyl-γ-phosphatidyl-glycerols (XII) and (XXII) differ by their melting points and chromatographic properties and that they do not undergo interconversion on silica gel chromatography in acid or neutral systems. Since synthetic 1-[(1′-oleoyl-2′-palmitoyl-glyceryl)-phosphoryl]-3-L-lysyl-glycerol was shown to be chromatographically indistinguishable from the natural lipoamino acid (P. P. M. Bonsen, G.H. de Haas and L.L.M. van Deenen, Biochemistry 6 (1967) 1114), the native compound must be the α-isomer." @default.
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- W2065203669 date "1968-02-01" @default.
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- W2065203669 title "On the structure of lipoamino acids" @default.
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- W2065203669 doi "https://doi.org/10.1016/0009-3084(68)90030-3" @default.
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