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• W2065205990 abstract "It has been found that for mono- and di-meso-phenyl-substituted octaethylporphyrin (OEPs), etioporphyrins, corresponding Zn complexes and OEP chemical dimers (with a meso-phenyl spacer) a drastic shortening of triplet lifetimes from a ms to μs timescale in deaerated toluene solutions at 295 K takes place without any changes of the spectral-kinetic parameters of the S0 and S1 states. The observed effects are connected with torsion librations of the phenyl ring around a single C–C bond in sterically encumbered porphyrins leading to non-planar dynamic distorted conformations in excited T1 states accompanied by an enhancement of the T1-state nonradiative deactivation pathways." @default.
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• W2065205990 date "1998-11-01" @default.
• W2065205990 modified "2023-09-27" @default.
• W2065205990 title "Unusual dynamic relaxation of triplet-excited meso-phenyl-substituted porphyrins and their chemical dimers at room temperatures" @default.
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• W2065205990 doi "https://doi.org/10.1016/s0009-2614(98)01096-3" @default.
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