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- W2065217844 endingPage "3271" @default.
- W2065217844 startingPage "3271" @default.
- W2065217844 abstract "Homogeneous catalysts for olefin polymerization such as metallocene or half-sandwich complexes containing the metals titanium, zirconium and hafnium, or other transition-metal coordination complexes can be functionalized with alkenyl groups and have then the potential to copolymerize with olefins to give heterogeneous catalysts. In a similar manner metallacyclic metallocene complexes with a metal-carbon sigma bond allow the catalytic insertion of olefins into this bond and produce heterogeneous catalysts. It is also possible to functionalize the active species of the cocatalyst methylalumoxane (MAO) and use it for self-immobilization processes. The high excess of MAO that is necessary in homogeneous solution can be reduced by more than 90% with this method." @default.
- W2065217844 created "2016-06-24" @default.
- W2065217844 creator A5035246423 @default.
- W2065217844 date "2005-01-01" @default.
- W2065217844 modified "2023-10-14" @default.
- W2065217844 title "Self-immobilizing catalysts and cocatalysts for olefin polymerization" @default.
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- W2065217844 doi "https://doi.org/10.1039/b506074p" @default.
- W2065217844 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16193144" @default.
- W2065217844 hasPublicationYear "2005" @default.
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