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- W2065220890 abstract "Hydrothermal reactions of lanthanide nitrates with selenic acid, sodium oxalate, and organic amines led to two series of new organically templated lanthanide oxalate–selenate hybrids with 2D-layer or 3D-network structures, namely, Ln2(SeO4)2(C2O4)(H2O)4·pip (Ln = Eu 1; Tb 2; Dy 3; Er 4; Yb 5) (pip = piperazine) and [H2pip]2[Ln2(SeO4)2(C2O4)3]·H2O (Ln = Er 6; Yb 7; Lu 8; Y 9). Their structures were established by X-ray single-crystal diffraction. Isostructural compounds 1–5 feature a 2D inorganic–organic hybrid neutral layer of Ln2(SeO4)2(C2O4)(H2O)4. The neutral piperazine molecules are located at the interlayer spaces and interconnect with the inorganic skeleton through hydrogen bonds. Compounds 6–9 are isostructural and possess 3D pillared layered architectures composed of lanthanide oxalate layers bridged by selenate anions (the pillar). The template cations are located at the tunnels of the structure. Compounds 1, 2, and 3 display emission bands in the red-, green-, and pink-light regions, respectively, and these compounds have lifetimes of 0.178, 0.962, and 0.276 ms, respectively. Compounds 6 and 7 both exhibit emission bands in the near-IR region. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
- W2065220890 created "2016-06-24" @default.
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- W2065220890 date "2007-11-19" @default.
- W2065220890 modified "2023-09-26" @default.
- W2065220890 title "Luminescent Organically Templated Lanthanide Oxalate–Selenate Hybrids" @default.
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- W2065220890 doi "https://doi.org/10.1002/ejic.200700744" @default.
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