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- W2065220910 abstract "The reaction of (C5H4tBu2)2Sm with AlH3 in ether or (C5H4tBu2)2Sm·THF with AlH3 in THF in the presence of excess of TMEDA and pentane involves the oxidation of Sm(2+) to Sm(3+), partial loss of Cp″-ligands and formation of the octanuclear complex Cp″5Sm4(AlH4)32Me2NC2H4NMe2, the cyclic metal core of which resembles a sitting frog. Atoms Sm1, Sm3 and Sm4 are coordinated with one Cp″-ligand each, while Sm2 is bonded with two Cp″-ligands. All Metals of the complex are bonded by μ2- and μ3-bridging hydrogens." @default.
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- W2065220910 date "1991-11-01" @default.
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- W2065220910 title "Crystal and molecular structures of the octanuclear aluminohydride samarium complex (η5-C5H3tBu2)Sm[(η2-H)2(η3-H)2Al(Me2NC2H4NMe2)]2 [(η5-C5H3tBu2)SmH]2[(η2-H)3Al(η2-H)Al(η2-H)3] [(η3-H)2Sm(η5-C5H3tBu2)2]" @default.
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- W2065220910 doi "https://doi.org/10.1016/0022-328x(91)86443-t" @default.
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