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- W2065221337 abstract "The spectra of odd-ring compounds, azulene, 1,2-benzazulene, 2-phenyl azulene, and indeno-azulene are compared with those of their corresponding regular isomers, naphthalene, phenanthrene, phenylnaphthalene, and benzfluorene in part from 1730 to 7500A. The five band systems found in the azulenes seem to correspond with respect to intensity, vibrational structure, and sequence to the five found in their corresponding isomers except that the former are shifted to lower frequencies. The lowest frequency band is shifted some 17,000 cm−1 to the red in the azulenes, which accounts for the color observed in these compounds, whereas the four transitions at higher frequencies are shifted about 8000 to 9000 cm−1 as compared with the corresponding regular isomers. Decreases in total oscillator strengths with non-linearity of these planar molecules as compared with the linear compounds (a type of C2v symmetry about the long axis) are noted as has previously been shown in the comparison of anthracene and phenanthrene, and tetracene and 1,2-benzanthracene and chrysene." @default.
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- W2065221337 date "1950-08-01" @default.
- W2065221337 modified "2023-09-27" @default.
- W2065221337 title "Spectral Resemblances between Azulenes and Their Corresponding Six-Carbon Ring Isomers" @default.
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- W2065221337 doi "https://doi.org/10.1063/1.1747858" @default.
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