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- W2065231657 abstract "Densities of aqueous solutions of mixtures of dibucaine hydrochloride (DCHC), a local anesthetic, and dodecyltrimethylammonium chloride (DTAC) were measured as functions of total molality. The apparent molar volumes of the mixtures were calculated from the density data. The molar volumes in the monomeric and micellar states were evaluated from the dependence of the apparent molar volume on the total molality. The critical micelle concentration (cmc) of the mixtures was determined from the break point of the apparent molar volume vs. the total molality curves, while the micellar composition was evaluated from the dependence of the cmc on the mole fraction of DTAC in the mixture. The composition diagram of micellization has a swollen cigar shape, slightly distorted in the composition range near the DTAC component; such a distortion indicates slightly non-ideal mixing between the hydrophobic groups of DCHC and DTAC molecules in the micelle. However, the molar volume of micellar state varies depending upon th..." @default.
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- W2065231657 date "1995-08-01" @default.
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- W2065231657 title "Volume Study on the Micelle Formation of Local Anesthetic Dibucaine Hydrochloride and Dodecyltrimethylammonium Chloride Mixtures" @default.
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- W2065231657 doi "https://doi.org/10.1246/bcsj.68.2159" @default.
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