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- W2065256670 abstract "Among the correlated electronic systems, BaVS3 which exhibits both itinerant and localized states as well as a subtle interplay betwen charge, orbital, spin and lattice degrees of freedom, is a model system. Its electronic structure consists in a broad quasi–one-dimensional (1D) dz2 band and two quasi-degenerate narrow e(t2g) bands. Pure BaVS3 exhibits a metal-insulator transition (MIT) driven by a Peierls instability in the dz2 band. We present a structural investigation showing that in chemically substituted Ba1- xSrxVS3 and in non-stoichiometric BaVS3- δ, the commensurate Peierls distortion of BaVS3 is replaced by an incommensurate modulation that we attribute to a charge ordering (CO) of the localized e(t2g) electrons. This unexpected structural feature is discussed in relationship with the concomitant drastic change of magnetic properties of the system." @default.
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- W2065256670 date "2010-01-01" @default.
- W2065256670 modified "2023-10-11" @default.
- W2065256670 title "Charge ordering in substituted and non-stoichiometric BaVS 3" @default.
- W2065256670 doi "https://doi.org/10.1209/0295-5075/89/27006" @default.
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