Matches in SemOpenAlex for { <https://semopenalex.org/work/W2065273924> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W2065273924 endingPage "35" @default.
- W2065273924 startingPage "29" @default.
- W2065273924 abstract "Aminopyridyl compound immobilization on glassy carbon (GC) was carried out by amine cation radical formation through electro-oxidation at GC in ethanol solution, and subsequently by chemical bonding of the radical to GC. The aminopyridyl group immobilized on GC takes part as a bridge between cobalt tetraphenylporphyrin (Co(II)TPP) and GC, where the nitrogen of the pyridyl group is coordinated as a fifth ligand of Co(II)TPP, being perpendicular to the porphyrin plane. The Co(II)TPP modified GC electrode was thus prepared by a bridging amine of 4-aminopyridine, 4-aminoethylpyridine, or imidazole in the electrochemical and chemical processes, which is denoted ‘CoTPP bonded GC’. Whereas Co(II)TPP physically attached to GC, denoted CoTPP|GC, was not able to reduce CO2 atE = −1.1V(SCE) in pH 6.3 phosphate buffer solution, ‘CoTPP bonded GC’ gave CO from CO2 electroreduction at that potential with 60% current efficiency. By polarization of ‘CoTPP bonded GC’ at hydrogen evolution potentials, Co(II)TPP stacked on ‘CoTPP bonded ’ is suggested to be converted to HCo(II)TPP, but Co(II)TPP on CoTPP|GC remains the same. Hydrogenated ‘CoTPP bonded GC’ is suggested to play an important role as one of the intermediates of CO2 electroreduction." @default.
- W2065273924 created "2016-06-24" @default.
- W2065273924 creator A5024627934 @default.
- W2065273924 creator A5080990617 @default.
- W2065273924 date "1997-11-01" @default.
- W2065273924 modified "2023-09-27" @default.
- W2065273924 title "Aminopyridyl cation radical method for bridging between metal complex and glassy carbon: cobalt(II) tetraphenylporphyrin bonded on glassy carbon for enhancement of CO2 electroreduction" @default.
- W2065273924 cites W1977398427 @default.
- W2065273924 cites W1984521685 @default.
- W2065273924 cites W2020772505 @default.
- W2065273924 cites W2026785149 @default.
- W2065273924 cites W2032216411 @default.
- W2065273924 cites W2042022091 @default.
- W2065273924 cites W2052244039 @default.
- W2065273924 cites W2069253016 @default.
- W2065273924 cites W2070159662 @default.
- W2065273924 cites W2077697112 @default.
- W2065273924 cites W2091911735 @default.
- W2065273924 cites W2092298304 @default.
- W2065273924 cites W2106056372 @default.
- W2065273924 cites W2996770971 @default.
- W2065273924 cites W4239885720 @default.
- W2065273924 doi "https://doi.org/10.1016/s0022-0728(97)00080-6" @default.
- W2065273924 hasPublicationYear "1997" @default.
- W2065273924 type Work @default.
- W2065273924 sameAs 2065273924 @default.
- W2065273924 citedByCount "66" @default.
- W2065273924 countsByYear W20652739242012 @default.
- W2065273924 countsByYear W20652739242014 @default.
- W2065273924 countsByYear W20652739242015 @default.
- W2065273924 countsByYear W20652739242016 @default.
- W2065273924 countsByYear W20652739242017 @default.
- W2065273924 countsByYear W20652739242018 @default.
- W2065273924 countsByYear W20652739242019 @default.
- W2065273924 countsByYear W20652739242020 @default.
- W2065273924 countsByYear W20652739242021 @default.
- W2065273924 countsByYear W20652739242022 @default.
- W2065273924 countsByYear W20652739242023 @default.
- W2065273924 crossrefType "journal-article" @default.
- W2065273924 hasAuthorship W2065273924A5024627934 @default.
- W2065273924 hasAuthorship W2065273924A5080990617 @default.
- W2065273924 hasConcept C131779359 @default.
- W2065273924 hasConcept C147789679 @default.
- W2065273924 hasConcept C161790260 @default.
- W2065273924 hasConcept C17525397 @default.
- W2065273924 hasConcept C178790620 @default.
- W2065273924 hasConcept C179104552 @default.
- W2065273924 hasConcept C185592680 @default.
- W2065273924 hasConcept C188027245 @default.
- W2065273924 hasConcept C2776422427 @default.
- W2065273924 hasConcept C2777869211 @default.
- W2065273924 hasConcept C2778401137 @default.
- W2065273924 hasConcept C2779480358 @default.
- W2065273924 hasConcept C33989665 @default.
- W2065273924 hasConcept C512735826 @default.
- W2065273924 hasConcept C515602321 @default.
- W2065273924 hasConcept C52859227 @default.
- W2065273924 hasConcept C544153396 @default.
- W2065273924 hasConcept C75473681 @default.
- W2065273924 hasConceptScore W2065273924C131779359 @default.
- W2065273924 hasConceptScore W2065273924C147789679 @default.
- W2065273924 hasConceptScore W2065273924C161790260 @default.
- W2065273924 hasConceptScore W2065273924C17525397 @default.
- W2065273924 hasConceptScore W2065273924C178790620 @default.
- W2065273924 hasConceptScore W2065273924C179104552 @default.
- W2065273924 hasConceptScore W2065273924C185592680 @default.
- W2065273924 hasConceptScore W2065273924C188027245 @default.
- W2065273924 hasConceptScore W2065273924C2776422427 @default.
- W2065273924 hasConceptScore W2065273924C2777869211 @default.
- W2065273924 hasConceptScore W2065273924C2778401137 @default.
- W2065273924 hasConceptScore W2065273924C2779480358 @default.
- W2065273924 hasConceptScore W2065273924C33989665 @default.
- W2065273924 hasConceptScore W2065273924C512735826 @default.
- W2065273924 hasConceptScore W2065273924C515602321 @default.
- W2065273924 hasConceptScore W2065273924C52859227 @default.
- W2065273924 hasConceptScore W2065273924C544153396 @default.
- W2065273924 hasConceptScore W2065273924C75473681 @default.
- W2065273924 hasIssue "1-2" @default.
- W2065273924 hasLocation W20652739241 @default.
- W2065273924 hasOpenAccess W2065273924 @default.
- W2065273924 hasPrimaryLocation W20652739241 @default.
- W2065273924 hasRelatedWork W1955121293 @default.
- W2065273924 hasRelatedWork W1965756756 @default.
- W2065273924 hasRelatedWork W1995848444 @default.
- W2065273924 hasRelatedWork W2032476486 @default.
- W2065273924 hasRelatedWork W2038352378 @default.
- W2065273924 hasRelatedWork W2061318898 @default.
- W2065273924 hasRelatedWork W2318978319 @default.
- W2065273924 hasRelatedWork W2611510330 @default.
- W2065273924 hasRelatedWork W4200513309 @default.
- W2065273924 hasRelatedWork W87484668 @default.
- W2065273924 hasVolume "437" @default.
- W2065273924 isParatext "false" @default.
- W2065273924 isRetracted "false" @default.
- W2065273924 magId "2065273924" @default.
- W2065273924 workType "article" @default.