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- W2065280278 abstract "Abstract The dinuclear titanium p-tert -butylthiacalix[4]arene complexes 1 and 2 after activation with methylaluminoxane have been tested as homogeneous catalysts for the polymerization of ethylene. The results show that the catalytic activity of 1, although still poor, is higher than those of the related mononuclear titanium complexes bearing calix[4]arene as ligand. The molecular weight of the polyethylene produced are high ( M W up to 1.4 × 10 6 Dalton) with broad molecular weight distribution. The polyethylenes have high melting point (133–142 °C) indicating a linear polymer microstructure which was confirmed by 13 C NMR analysis." @default.
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- W2065280278 date "2009-07-01" @default.
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- W2065280278 title "Ethylene polymerization promoted by dinuclear titanium p-tert-butylthiacalix[4]arene complexes" @default.
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- W2065280278 doi "https://doi.org/10.1016/j.eurpolymj.2009.04.014" @default.
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