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• W2065287100 abstract "The color of niobium phosphate glasses ranges from clear to deep blue depending on their thermal history. In this study, a glass with the nominal composition (mole %) 23K2O·40Nb2O5·37P2O5 was treated in oxidizing and reducing atmospheres at temperatures around Tg (730 °C) and the color at room temperature was analyzed using optical spectroscopy. Electron spin resonance (ESR) spectroscopy shows that the blue color is associated with the presence of Nb4 + ions, which oxidize to Nb5 + in the clear glasses. Bleaching kinetics were determined from a series of heat treatments below Tg in flowing oxygen, and analyzed with an diffusion model that indicated an activation energy of 150 ± 31 kJ/mol." @default.
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• W2065287100 date "2014-10-01" @default.
• W2065287100 modified "2023-10-02" @default.
• W2065287100 title "Color bleaching and oxygen diffusion in a niobium phosphate glass" @default.
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• W2065287100 doi "https://doi.org/10.1016/j.jnoncrysol.2013.11.004" @default.
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