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- W2065288444 abstract "Heat treated manganese dioxide is partially lithiated using butyl-lithium to determine the changes in crystal structure, chemical composition and morphology upon reduction, as a means of simulating its discharge behaviour in a non-aqueous battery cathode. As reduction proceeds, and lithium ions are inserted into the heat treated electrolytic manganese dioxide (EMD) structure, the material undergoes a phase transition to LiMn2O4. This new phase is further reduced to Li2Mn2O4. Reduction initially results in a 56% decrease in the surface area of the material; however, at higher degrees of reduction a slight increase in this value is observed, as a consequence of the strain placed on the lattice through continued lithium insertion." @default.
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- W2065288444 date "2012-07-01" @default.
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- W2065288444 title "Characterisation of chemically lithiated heat-treated electrolytic manganese dioxide" @default.
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- W2065288444 doi "https://doi.org/10.1016/j.materresbull.2011.05.027" @default.
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