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- W2065304844 abstract "The hydrogen–deuterium exchange reactions of methane in a deuterium stream were studied by a pulse experiment over a reduced nickel (Ni1373 prepared from nickel oxide calcined at 1373 K, and Ni773 prepared from nickel oxide calcined at 773 K) and K2O promoted reduced nickel (K-Ni1373 and K-Ni773). Ni1373 had a higher exchange activity than Ni773. The effects of the addition of K2O resulted in the decrease in the exchange activity due to the inhibition of step defect sites and/or the promotion of the change of nickel crystal structure. High activity of Ni1373 could be due to that the Ni1373 had the surface of a higher Ni(1 0 0)/Ni(1 1 1) ratio." @default.
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- W2065304844 date "2010-04-01" @default.
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- W2065304844 title "Hydrogen–deuterium exchange of methane on nickel and potassium promoted nickel prepared by the reduction of nickel oxide" @default.
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- W2065304844 doi "https://doi.org/10.1016/j.molcata.2010.01.005" @default.
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