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- W2065324364 abstract "In this publication we are reporting for the first time on examples of the redox behavior of enamines and complexes derived from 1-alkylpyrazolones. Cyclic voltammetry experiment was performed on three enamines derived from 4-acyl-1-(n-hexyl)-3-methylpyrazol-5-ol and their chloromanganese(III) and nitridomanganese(V) complexes. The ligands have an irreversible oxidation potential of 1.1 V. Chloromanganese(III) complexes are quasi-reversible with an E1/2 of 0.1 V. Nitridomanganese(V) complexes are also quasi-reversible, with E1/2 potentials of 0.95 V. However, for nitridomanganese(V) complexes reversibility increases as the scan speed raises from 100 to 3000 mV·s-1" @default.
- W2065324364 created "2016-06-24" @default.
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- W2065324364 date "2005-09-01" @default.
- W2065324364 modified "2023-10-16" @default.
- W2065324364 title "CYCLIC VOLTAMMETRY OF 1-(n-HEXYL)-3-METHYL-5-PYRAZOLONE-BASED ENAMINES AND THEIR CHLOROMANGANESE(III) AND NITRIDOMANGANESE(V) COMPLEXES" @default.
- W2065324364 doi "https://doi.org/10.4067/s0717-97072005000300009" @default.
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