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• W2065361810 startingPage "3013" @default.
• W2065361810 abstract "Shear viscosity measurements over the temperature interval 23 –− 124 °C (5×10−2– 108 P) and shear impedance measurements at 88 MHz over the interval −75–−130°C have been performed for concentrated aqueous lithium chloride solutions in the concentration range R=4.49 – 5.77 where R is the mole ratio of water to salt. Average shear relaxation times, 〈 τs 〉, have been calculated from these results and compared with average conductivity relaxation times, 〈 τσ 〉, reported previously by Moynihan, Bressel, and Angell. 〈 τs 〉 and 〈 τσ 〉 are within 30% of one another at the low viscosity end ( ∼104 P) of the range of comparison, but at higher viscosities the 〈τs 〉/〈τσ 〉 ratio becomes significantly larger than unity (2–3 at the highest viscosities for which data are available). Estimated 〈τs 〉/〈τσ 〉 ratios for other ionic liquids suggest that the occurrence of 〈τs 〉/〈τσ 〉 ratios greater than unity at high visosities may be a common phenomenon. Description of the shear relaxation process for concentrated LiCl—H2O solutions is found to require a fairly broad, asymmetric (Cole—Davidson) distribution of relaxation times." @default.
• W2065361810 created "2016-06-24" @default.
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• W2065361810 date "1971-09-15" @default.
• W2065361810 modified "2023-10-14" @default.
• W2065361810 title "Comparison of Shear and Conductivity Relaxation Times for Concentrated Lithium Chloride Solutions" @default.
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• W2065361810 doi "https://doi.org/10.1063/1.1676531" @default.
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