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• W2065371567 abstract "(R1−xCax)MnO3−δ (R: Tb, Ho, Y) solid solutions with the orthorhombic perovskite-type structure were synthesized and their electrical resistivity and thermoelectric power were measured in the temperature range 80 to 1000 K. At low temperature, the electrical properties of (R1−xCax)MnO3−δ are explained by the variable range hopping of electrons model. At high temperature, hopping conduction occurs in the composition range 0.4 ≦ x ≦ 0.6, while metal-insulator transition occurs in the range 0.7 ≦ x ≦ 0.9. Transition temperature increases with increasing average MnO distance. It is concluded that the increase in MnO distance enhances the magnitude of the electrostatic field, and consequently the transition temperature is raised. (R1−xCax)MnO3−δ (R: Tb, Ho, Y, 0.7 ≦ x ≦ 0.9) are candidates as high temperature thermoelectric conversion materials." @default.
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• W2065371567 date "1991-05-01" @default.
• W2065371567 modified "2023-09-30" @default.
• W2065371567 title "Metal-insulator transition and thermoelectric properties in the system (R1−Ca )MnO3− (R: Tb, Ho, Y)" @default.
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• W2065371567 doi "https://doi.org/10.1016/0022-4596(91)90248-g" @default.
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