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- W2065374291 abstract "(100-x) LiClO 4-x SiO 2 (x is mol %) solid composite electrolytes in various compositions were synthesized by modified sol-gel process with sintering at 200 °C. The electrical and structural properties of the composites were investigated. The ionic conductivity of the composites increased with mol % of the dispersoid and then decreased. The highest conductivity was obtained for x = 50 mol % with a value of 4.06 × 10 -7 S cm -1 at room temperature. The enhancement in conductivity was more than two orders of magnitude when compared to the host material. The higher conductivity in the SiO 2 dispersed system was interpreted in terms of space charge layer and percolation theory. The temperature dependence of conductivity of all samples were Arrhenian in nature and exhibited a maximum of 10 -3 S cm -1 at T = 140 °C for x = 50 mol %. XRD spectra showed presence of heterogeneous phase of LiClO 4 -SiO 2 crystalline peaks." @default.
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- W2065374291 date "2011-12-01" @default.
- W2065374291 modified "2023-09-25" @default.
- W2065374291 title "Characterization of LiClO<sub>4</sub>-SiO<sub>2</sub> Composite Electrolyte Prepared by Modified Sol-Gel Method" @default.
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- W2065374291 doi "https://doi.org/10.4028/www.scientific.net/amr.415-417.442" @default.
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