FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2065384906> ?p ?o ?g. }

• W2065384906 endingPage "12549" @default.
• W2065384906 startingPage "12548" @default.
• W2065384906 abstract "The intramolecular 13C kinetic isotope effects for the ring-opening of cyclopropylcarbinyl radical were determined over a broad temperature range. The observed isotope effects are unprecedentedly large, ranging from 1.062 at 80 °C to 1.163 at −100 °C. Semiclassical calculations employing canonical variational transition-state theory drastically underpredict the observed isotope effects, but the predicted isotope effects including tunneling by a small-curvature tunneling model match well with experiment. These results and a curvature in the Arrhenius plot of the isotope effects support the recently predicted importance of heavy-atom tunneling in cyclopropylcarbinyl ring-opening." @default.
• W2065384906 created "2016-06-24" @default.
• W2065384906 creator A5007886088 @default.
• W2065384906 creator A5018010226 @default.
• W2065384906 creator A5068360992 @default.
• W2065384906 creator A5068671141 @default.
• W2065384906 creator A5079974007 @default.
• W2065384906 creator A5089781679 @default.
• W2065384906 date "2010-08-19" @default.
• W2065384906 modified "2023-10-18" @default.
• W2065384906 title "Experimental Evidence for Heavy-Atom Tunneling in the Ring-Opening of Cyclopropylcarbinyl Radical from Intramolecular ¹²C/¹³C Kinetic Isotope Effects" @default.
• W2065384906 cites W1512716428 @default.
• W2065384906 cites W1644500305 @default.
• W2065384906 cites W1967411982 @default.
• W2065384906 cites W1982710154 @default.
• W2065384906 cites W1983725493 @default.
• W2065384906 cites W1984715913 @default.
• W2065384906 cites W2005070314 @default.
• W2065384906 cites W2024070716 @default.
• W2065384906 cites W2030802212 @default.
• W2065384906 cites W2041558591 @default.
• W2065384906 cites W2042612222 @default.
• W2065384906 cites W2045636278 @default.
• W2065384906 cites W2046791726 @default.
• W2065384906 cites W2049902668 @default.
• W2065384906 cites W2083114442 @default.
• W2065384906 cites W2092743359 @default.
• W2065384906 cites W2156557397 @default.
• W2065384906 cites W2950027073 @default.
• W2065384906 cites W3004781971 @default.
• W2065384906 cites W3005333729 @default.
• W2065384906 cites W4292404993 @default.
• W2065384906 doi "https://doi.org/10.1021/ja1055593" @default.
• W2065384906 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/2935944" @default.
• W2065384906 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20722415" @default.
• W2065384906 hasPublicationYear "2010" @default.
• W2065384906 type Work @default.
• W2065384906 sameAs 2065384906 @default.
• W2065384906 citedByCount "83" @default.
• W2065384906 countsByYear W20653849062012 @default.
• W2065384906 countsByYear W20653849062013 @default.
• W2065384906 countsByYear W20653849062014 @default.
• W2065384906 countsByYear W20653849062015 @default.
• W2065384906 countsByYear W20653849062016 @default.
• W2065384906 countsByYear W20653849062017 @default.
• W2065384906 countsByYear W20653849062018 @default.
• W2065384906 countsByYear W20653849062019 @default.
• W2065384906 countsByYear W20653849062020 @default.
• W2065384906 countsByYear W20653849062021 @default.
• W2065384906 countsByYear W20653849062022 @default.
• W2065384906 countsByYear W20653849062023 @default.
• W2065384906 crossrefType "journal-article" @default.
• W2065384906 hasAuthorship W2065384906A5007886088 @default.
• W2065384906 hasAuthorship W2065384906A5018010226 @default.
• W2065384906 hasAuthorship W2065384906A5068360992 @default.
• W2065384906 hasAuthorship W2065384906A5068671141 @default.
• W2065384906 hasAuthorship W2065384906A5079974007 @default.
• W2065384906 hasAuthorship W2065384906A5089781679 @default.
• W2065384906 hasBestOaLocation W20653849062 @default.
• W2065384906 hasConcept C120398109 @default.
• W2065384906 hasConcept C121332964 @default.
• W2065384906 hasConcept C135889238 @default.
• W2065384906 hasConcept C147597530 @default.
• W2065384906 hasConcept C147789679 @default.
• W2065384906 hasConcept C149635348 @default.
• W2065384906 hasConcept C161790260 @default.
• W2065384906 hasConcept C164304813 @default.
• W2065384906 hasConcept C178790620 @default.
• W2065384906 hasConcept C184779094 @default.
• W2065384906 hasConcept C185544564 @default.
• W2065384906 hasConcept C185592680 @default.
• W2065384906 hasConcept C195065555 @default.
• W2065384906 hasConcept C2524010 @default.
• W2065384906 hasConcept C26873012 @default.
• W2065384906 hasConcept C2780378348 @default.
• W2065384906 hasConcept C33923547 @default.
• W2065384906 hasConcept C41008148 @default.
• W2065384906 hasConcept C535169671 @default.
• W2065384906 hasConcept C58312451 @default.
• W2065384906 hasConcept C58364064 @default.
• W2065384906 hasConcept C62520636 @default.
• W2065384906 hasConcept C69928629 @default.
• W2065384906 hasConcept C71240020 @default.
• W2065384906 hasConcept C75079739 @default.
• W2065384906 hasConcept C84114770 @default.
• W2065384906 hasConcept C86183883 @default.
• W2065384906 hasConcept C8739425 @default.
• W2065384906 hasConcept C89031862 @default.
• W2065384906 hasConcept C95121573 @default.
• W2065384906 hasConceptScore W2065384906C120398109 @default.
• W2065384906 hasConceptScore W2065384906C121332964 @default.
• W2065384906 hasConceptScore W2065384906C135889238 @default.
• W2065384906 hasConceptScore W2065384906C147597530 @default.
• W2065384906 hasConceptScore W2065384906C147789679 @default.
• W2065384906 hasConceptScore W2065384906C149635348 @default.
• W2065384906 hasConceptScore W2065384906C161790260 @default.
• W2065384906 hasConceptScore W2065384906C164304813 @default.
• W2065384906 hasConceptScore W2065384906C178790620 @default.

• next