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- W2065388870 abstract "Stress relaxation mechanisms were investigated, on three types of EPT polymers, in air at 109°C. These polymers differ only in the structure of the cross-linkage in which there is a carbon–carbon bond, a polysulfide linkage (–Sx–) or a monosulfide linkage (–S–).All the stress relaxation of a peroxide-cured EPT polymer is not due to the oxygen-induced cleavage of the main chain but to a physical flow. In the case of a sulfur-cured EPT polymer, the relaxation curve is divided into three straight lines by using the procedure X when logf(t)/f(0) is plotted against t. It was concluded that this graph could be attributed to an interchange reaction between the polysulfide linkage and an oxidative cleavage of the monosulfide linkage. On the other hand, a TT-cured EPT polymer gave a plot with a straight line. This stress relaxation could be explained by an oxidative cleavage of the monsulfide linkage.Further, we have investigated the degree of agreement between the theoretical relation proposed by us and experimental results relating to TT-cured natural rubber. In this cross-linked polymer, both scissions of main chain and cross-linkage occur at the same time." @default.
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- W2065388870 date "1971-05-01" @default.
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- W2065388870 title "Chemorheology of Cross-linked Polymers. Chemorheological Treatment of Cross-linked Polymers" @default.
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- W2065388870 doi "https://doi.org/10.1295/polymj.2.328" @default.
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