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- W2065403458 abstract "An ion-selective electrode using ionophore 2′-picolyl sym-dibenzo-16-crown-5 ether as membrane carrier, sodium tetraphenylborate (NaTPB) as an anion excluder, and 2-nitrophenyl-octyl ether (NOPE) as the plasticing solvent mediator has been successfully developed. This electrode exhibits al in ear response with a slope of 42 mV/decade in concentration ranging from 10−5 molL−1 to 10−1 molL−1, slightly larger than the 30 mV expected from the one-to-one complex. The reason for the super-Nernstain slope is the partial dimmer formation in side the membrane of the electrode, because this dimmer [Cu(C25H27NO6)2(H2O)2] 2ClO4, has been isolated and confirmed by single crystal X-ray crystallography. The detection limit for the cop per (II) ion was estimated to be 1 × 10−6 molL−1. Electrades composed of other plasticing solvent mediators such as tris(2-ethylhexyl) phosphate (TOP), bis (2-ethylhexyl) sebacate (DOS) and dibutyl phthalate (DBP) were also investigated. Stability constants (logKs) of the two to one and the one to one 2-picolylsym-dibenzo-16-crown-5 ether-Cu (II) complexes have been determined by potentiometric titration in methanol." @default.
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- W2065403458 date "2001-08-01" @default.
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- W2065403458 title "Characteristics of Lariat Crown Ether-Copper (II) Ion-Selective Electrodes" @default.
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- W2065403458 doi "https://doi.org/10.1002/jccs.200100105" @default.
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